Kavli Affiliate: Gerbrand Ceder
| Summary:
Disordered rock-salt with Li-excess (DRX) cathode phases within the Li-Mn-Ti-O (LMTO) composition space have recently been extensively studied, as they promise to deliver exceptional energy density at low cost in Li-ion batteries. The continued development of LMTO DRX with improved power density and cycling stability requires optimization of the composition and particle size/morphology, which are determined by synthesis conditions such as annealing temperatures and hold times. These challenges motivate our investigation of the phase diagram of the LMTO rock-salt phase space, with a focus on understanding the stability of DRX by quantifying the order-disorder transition temperature ($T_textdisord$) as a function of composition. We harness first-principles calculations and X-ray diffraction experiments to establish the LMTO phase diagram, which lies within the LiMnO$_2$ — Li$_2$MnO$_3$ — Li$_2$TiO$_3$ pseudo-ternary. Our calculations predict that the LMTO phase diagram at elevated temperature ($700 – 1300$ C) is composed of three phases: DRX, orthorhombic LiMnO$_2$, and layered Li$_2$Mn$_text1-y$Ti$_texty$O$_3$ ($0 < texty < 1$). $T_textdisord$ decreases significantly as off-stoichiometry is introduced to the end-point compositions, resulting in a eutectoid phase diagram. Importantly, a significant range of LMTO compositions containing small to moderate fractions of Li-excess and Ti doping (relative to LiMnO$_2$) have $T_textdisord$ spanning $700 – 900$ C. These temperatures are substantially lower than conventional DRX synthesis temperatures ($geq 1000$ C), suggesting the promise of decreasing synthesis temperatures for specific DRX compositions. The compositions containing moderate to high fractions of Mn$^4+$ instead have much greater $T_textdisord$ and phase separation to layered Li$_2$MnO$_3$ becomes highly favored.
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