Kavli Affiliate: Joseph Falson | Summary:Conventional oxide epitaxy approaches face challenges when the oxidation conditions of constituent elements differ significantly. Here we demonstrate that V–O thin films can serve as solid-phase precursors for epitaxial AlV$_2$O$_4$, comprising a pyrochlore V$^2.5+$ network coexisting with AlO$_4$ tetrahedra within the spinel structure. The epitaxial AlV$_2$O$_4$/Al$_2$O$_3$ (0001) heterostructures are realized […]
Continue.. AlV$_2$O$_4$ thin films via in-situ interfacial topotaxy