Kavli Affiliate: Rudolf Podgornik | Summary:We study the effect of asymmetry in solvent and ionic size on the equilibrium properties of multivalent ionic solutions near a charged surface. For a single ionic species in solution, we derive a generalized Grahame equation at the charged surface. For general size ratio between the ions and the solvent, […]
Continue.. The effects of ionic valency and size asymmetry on counterion adsorption